Tonight, my face was burning hot due to chili.
While cooking supper, I sliced one jalapeno pepper and removed the seeds by hand. Without washing my hand, I unconsciously touched my face. After a while my face felt so hot. I washed my hands then washed my face with soap. Still the burning sensation persisted with more intensity because I felt it in my eyes too.
I put honey on my face. It did not work. So, I searched the internet for a quick cure. The first one is to slather oil on the burn, it did not work. By this time my face and eyes are so red I was worried that my face was really burning inside. The next one I tried is to use lemon juice. I squeezed about 2 tablespoons and applied it on my face. In a few seconds the burning sensation gradually subsided. It actually worked.
Details here: http://skinverse.com/how-to-get-rid-of-chili-burn.html